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Nd doped Yttrium
Vanadate (Nd3+:YVO4) is one of the most effective and
advanced materials for diode pumped lasers. Compactly designed
Nd3+:YVO4 lasers with green, red and blue light output are really
perfect means for material processing, spectroscopy, medical
diagnostics, laser printing and other applications. Compared
to Nd3+:YAG and Nd3+:YLF, Nd3+:YVO4 diode pumped lasers have:
wide absorption bandwidth, low lasing threshold, high slope
efficiency, large luminescent cross-section, linearly polarized
emission and single-mode output.
Yttrium Vanadate doped with Er3+ or
Yb3+ and also with a combination of Er3+, Yb3+ (YVO4:Er3+;
YVO4:Yb3+; YVO4:Er3+,Yb3+) work on wavelenghts of 1.54,
1.61 µm and are used in eyesafe laser applications. In contrast
to Er3+, Yb3+ doped phosphate glass, Er3+, Yb3+:YVO4 crystals
can be used in CW mode with high pump energy and high efficiency.
Its thermal conductivity is much higher than that of glass and
this improves pump characteristics of the laser and relaxes
cooling requirements. Yb3+:YVO4 has a wide absorption bandwidth
at 0.98 µm and can generate with high effectivity at 1.02 µm
due to low losses of the pump energy.
Combined Yttrium Vanadate (YVO4
/Nd3+:YVO4) crystals combined during growth process
are principially different from analoguous composite crystals,
produced by bonding undoped and Nd3+ doped YVO4 crystals utilizing
thermal diffusion. In case of thermal diffusion at the bonding
interface optical losses can be examined, which lead to lower
laser efficiency, and at certain laser conditions cracks can
appear on this interfaces resulting in damage of the optical
element. The combined crystals do not have such bonding interfaces
and for this reason mentioned problems do not occur. The combined
crystals have about 10-15% higher output generation characteristics
and a higher damage threshold compared to composite crystals.
New Nd3+-doped gadolinium vanadate
crystals Nd3+:GdVO4 allow to create effective
diode-pumped lasers for applications in medicine and technique.
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