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Light output
(LO) is the coefficient of conversion of ionizing radiation
into light energy. Having the highest LO, NaI(Tl) crystal is
the most popular scintillation material. Therefore, LO of NaI(Tl)
is taken to be 100%. Light output of other scintillators is
determined relative to that of NaI(Tl) (%). LO (Photon/MeV)
is the number of visible photons produced in the bulk of scintillator
under gamma radiation.
Scintillation Decay time
is the time required for scintillation emission to decrease
to e-1 of its maximum.
Energy resolution
is the full width of distribution, measured at half of its maximum
(FWHM), divided by the number of peak channel, and multiplied
by 100. Usually Energy resolution is determined by using a 137Cs
source. The above description is illustrated in Fig. 1. Energy
resolution shows the ability of a detector to distinguish gamma-sources
with slightly different energies, which is of great importance
for gamma-spectroscopy.
Emission spectrum
is the relative number of photons emitted by scintillator as
a function of wavelength. The Emission spectrum is shown in
Fig. 2. The intensity maximum corresponds to the Imax wavelength
shown in the table. For coefficient detection of emitted photons,
the maximum of PMT quantum efficiency should coincide with Imax.
Background is a quantity
determined as a number of luminescent pulses emitted by radioactive
substance within 1 second in the bulk of the scintillator with
the weight of 1 kg.
Most scintillation crystals reveal
a number of luminescent components. The main component corresponds
to Decay time, however less intense and slower ones also exist.
Commonly, the strength of these components is estimated by using
the intensity of a scintillator's glow, measured at specified
time after the Decay time. Afterglow is the ratio of the intensity
measured at this specified time (usually, after 6 ms) to the
intensity of the main component measured at Decay time.
Complex oxide crystals Gadolinium
Silicate doped with Cerium (Gd2SiO5(Ce) or GSO), BGO, CWO and
PWO have a number of advantages over alkali halide
crystals: high effective atomic number, high density, good energy
resolution in the energy region over 5 MeV, low afterglow, and
non-hygroscopicity. Due to these features, detectors with oxide
crystals are fail-safer, have no need of hermetization, and
have mass and volume several times less than Alkali Halide analogues
at the same detection efficiency. Yet oxide scintillators are
characterized by lower light output and somewhat lower energy
resolution at energies less than 5 MeV.
Bismuth Germanate (Bi4Ge3012
or BGO) is one of the most widely used scintillation
materials of the oxide type. It has high atomic number and density
values. Detectors based on BGO have volume 10 - 4 times and
mass 5 - 7 times less than those with Alkali Halide scintillators.
BGO is mechanically strong enough, rugged, non-hygroscopic,
and has no cleavage .BGO has an extreme high density of 7.13
g /cm3 and has a high Z value which makes these crystals very
suitable for the detection of natural radioactivity (U, Th,
K), for high energy physics applications (high photofraction)
or in compact Compton suppression spectrometers.
BGO detectors are characterized by high energy resolution in
the energy range 5 - 20 MeV, a relatively short decay time;
its parameters remain stable up to the doses of 5 x 104 Gy;
large-size single crystals are possible to obtain. Due to these
features, BGO crystals are used in high-energy physics (scintillators
for electromagnetic calorimeters and detecting assemblies of
accelerators), spectrometry and radiometry of gamma-radiation,
positron tomography
Cadmium Tungstate (CdWO4 or
CWO) has high density and atomic number values. Therefore,
for CWO, the light output is 2.5 - 3 times higher than that
of Bismuth Germanate. Due to low intrinsic background and afterglow
and to rather high light output of CWO, the most suitable areas
of its application are spectrometry and radiometry of radionuclides
in extra-low activities. CWO is the most widely used scintillator
for computer tomography. A rather great decay time value (3
- 5 Cls) is a significant feature of CWO which restricts the
possibilities of its application in many cases.
Lead Tungstate (PbWO4 or PWO)
is a heavy (density = 8.28 g/cm3, Z = 73) and fast (decay time
= 3 - 5 ns) scintillation material. It has the least radiation
length and Moliere radius values (0.9 and 2.19, respectively)
among all known scintillators. Radiation damage appears at doses
exceeding 105 Gy. Yet the light output of PWO is as low as about
1% of Csl(TI), so that the material can be used in high-energy
physics only.
Double Natrium-Bismuth Tungstate
(NaBi(WO4)2 or NBWO) is a new material that can be
used as a Cherenkov radiator for particle detection. This crystal
has scheelite structure of the space group C64h. Na+ and Bi3+
cations are statistically distributed among structural 4a positions
(structural-statistic disorder). The unit cell contains two
formula units. The unit cell parameters according to x-ray data
are: a=5,281±0,001 Å; c=11,510±0,002 Å; the density r=7,588±0,004
g/cm3. Optical and luminescent properties of NBW are scarcely
studied because this crystal can hardly be used as a scintillator
due to low quantum yield of its luminescence. It was reported
that X-ray luminescence spectrum has maximum ~520 nm and the
luminescence intensity is about 5% of BGO intensity.
Thallium doped Sodium Iodide
NaI(Tl) is the most widely used scintillation material.
NaI(TI) is used traditionally in nuclear medicine, environmental
measurements, geophysics, medium-energy physics, etc. The fact
of its great light output among scintillators, convenient emission
range (in coincidence with maximum efficiency region of photomultiplier
(PMT) with bialkali photocatodes), the possibility of large-size
crystals production, and their low prices compared to other
scintillation materials compensate to a great extent for the
main Nal(TI) disadvantage. Which is namely the hygroscopicity,
on account of which NaI(TI) can be used only in hermetically
sealed assemblies. Varying of crystal growth conditions, dopant
concentration, raw material quality, etc. makes it possible
to improve specific parameters, e.g., to enhance the radiation
resistance, to increase the transparency, and to reduce the
afterglow. For specific applications, low-background crystals
can be grown. NaI(TI) crystals with increased dopant concentration
are used to manufacture X-ray detectors of high spectrometric
quality. NaI(TI) is produced in two forms: single crystals and
polycrystals. The optical and scintillating characteristics
of the material are the same in both states. In some cases of
application, however, the use of the polycrystalline material
allows coping with a number of additional problems. First, a
press forging makes it possible to obtain crystals with linear
dimensions exceeding significantly than those of grown single
crystals. Second, the polycrystals are ruggedized, which is
important in some cases. Moreover, NaI(TI) polycrystals do not
possess the perfect cleavage, so the probability of their destruction
in the course of the use is reduced. The use of extrusion in
converting NaI(TI) into the polycrystalline state makes it also
possible to obtain complex-shaped parts without additional expensive
machining.
The most important feature of Cesium
Iodide crystals doped with Thallium CsI(Tl) is their
emission spectrum having the maximum at 550 nm, which allows
photodiodes to be used to detect the emission. The use of a
scintillator-photodiode pair makes it possible to diminish significantly
the size of the detecting system (due to the use of photodiode
instead of PMT), to do without high-voltage supply source, and
to use detecting systems in magnetic fields. The high radiation
resistance (up to 102 Gy) allows CsI(TI) to be used in nuclear,
medium and high-energy physics. Special treatment ensures obtaining
of CsI(TI) scintillators with a low afterglow (less than 0.1%
after 5 ms) for the use in tomographic systems.
Cesium Iodide doped with Sodium
CsI(Na) is a widely used material nowadays. High light
output (85% of that of NaI(TI)), emission in the blue spectral
region (in coincidence with the maximum sensitivity range of
the most popular PMT with bialkali photocatodes), and substantially
lower hygroscopicity in comparison with that of NaI(TI) makes
this material a good alternative for NaI(TI) in many standard
applications. The temperature dependence of light output has
its maximum at 80°C. This makes it possible to use CsI(Na) the
scintillation material at elevated temperatures. The decay time
of CsI(Na) depends on the dopant concentration and varies in
the range of 500 - 700 ns.
Zinc Selenide ZnSe(Te)
scintillation material was created especially for matching with
photodiode, which its emission maximum is at 640 nm. Matching
coefficient between scintillator and photodiode is up to 0.9.
ZnSe scintillators are sharply different from ZnS. "Fast"
ZnSe has the time decay of 3 - 5 µs, "slow" - 30 -
50 µs. These are used preferably for X-rays and gamma-particle
registration. Crystals ZnSe(Te) do not have very good transparency.
Relative to CsI(Tl), light output for X-rays with E<100 keV
(CsI(Tl)=100%) is up to 170% at 2 mm thickness. Non-uniformity
is usually less than 1%. Crystals ZnSe(Te) are non-higroscopic
and good enough for mechanical treatment without any cleavage.
Standard ZnSe(Te) boules have a diameter of 24 mm. Diameters
up to 40 mm are available on request.
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