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Crystals of group RE:MPb2X5
( M=K, Rb X= Cl, Br) is a new promising active media
for lasers, operating on different wavelengths in the range
from UV to mid-IR, including those for TV amplifiers with diode
pumping. Interest to this material, which has high RE segregation
coefficients and a set of attractive properties increased considerably
to date, while:
• Low energy of phonons in halogenides provides
mainly radiative transitions between adjacent levels with the
gap = 1500 cm-1 as a result emission bands cover the wide spectral
region from UV (transitions from upper excited levels) to 9-10
µm in the mid-IR (transitions within both excited and ground
RE multiplets);
• Complex of long decay times for lower states,
high values of absorption cross-sections and low rates of the
nonradiative multiphonon relaxation makes these crystals promising
for their application as active media for UV/VIS lasers with
up-conversion pumping;
• Broad variations of RE type and dopant
concentrations are possible for RE:MPb2X5 crystals;
• Relatively broad, structureless luminescence
bands in RE:MPb2X5 crystals allow fine tuning of the stimulated
emission frequency;
• To date stimulated emission has been obtained
for 1.064 µm (Nd), 1.3 and 2.4 µm (Dy) and 4.6 µm (Er);
• It is important that intense absorption
bands match the laser diodes emission for many RE ions in MPb2X5
crystals.
Protective/antireflection coatings may be performed on the aperture
surfaces of the produced elements. Typical sizes of optical
elements are 4 x 4 x (5-15) mm3.
Rubidium Iodide (RbI)
Rubidium Chloride (RbCl)
Rubidium Bromide (RbBr)
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