|
Thallium Halogenide
crystals (KRS-5, KRS-6) are designed for transmission,
refraction and focusing of visible and infrared radiation. KRS5
is used extensively in spectroscopy for ATR prisms, windows
and lenses. In conjunction with Germanium, KRS5 can also be
used in athermalised IR imaging systems. Wide transparence range,
radiation, thermal and vibrational stability, low water solubility
make these crystals valuable for applications in optical devices
working in atmosphere conditions and outer space without special
protection. Low absorbtion in MID-IR and large refractive index
make these crystals suitable for internal reflection elements.
KRS-5 is used for
attenuated total reflection prisms, IR windows and lenses where
transmission in the 0.6 µm - 40 µm range is desired. It has
a tendency to cold-flow and change its shape with time. KRS-5
is only slightly soluble in water but can be dissolved in alcohol,
nitric acid, and aqua regia. KRS-5 (TlBr-TlI) is a gorgeous
red crystal commonly used for attenuated total reflection prisms
for IR spectroscopy. It is also used as an infrared transmission
window in gas and liquid sample cells used with FTIR spectrophotometers
in place of Potassium Bromide (KBr) or Cesium Iodide (CsI) for
analysis of aqueous samples that would attack KBr or CsI optics.
It has a wide transmission range and is virtually insoluble
in water. It is a useful alternative to AgCl since it is not
photo-sensitive and for ATR applications it will transmit well
beyond the 18 micron useful range of ZnSe. KRS-5 is considered
toxic, but in our opinion it is safe for IR spectroscopic applications
when properly handled.
<<<Back
|