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Silver Thiogallate
(AgGaS2 or AGS) is transparent from 0.53 to 12 µm and
has been demonstrated to be an efficient frequency doubling crystal
for infrared radiation such as the 10.6 µm output of CO2 lasers.
Although nonlinear optical coefficient is the lowest among the
above mentioned infrared crystals, its high short wavelength transparency
edging at 550 nm is used in OPOs pumped by Nd:YAG laser; in numerous
difference frequency mixing experiments using diode, Ti:Sapphire,
Nd:YAG and IR dye lasers covering 3–12 µm range; direct infrared
countermeasure systems, and SHG of CO2 laser.
With suitable pump lasers, AgGaS2 optical parametric oscillators
(OPO's) can produce continuously tunable radiation over a wide
range of wavelengths in the infrared. Using 2050 nm pump laser,
an optimally designed AgGaS2 OPO is tunable from about 2.5 to
12.0 µm. The output range can be extended by the sum or difference
frequency mixing (SFM/DFM). This crystal has a high non-linear
coefficient, high damage threshold, and a wide transmission range.
It also has low optical absorption and scattering, low wavefront
distortion. Among commercially available crystals, AgGaS2 has
the highest figure of merit for non-linear interactions in the
near and deep infrared. The availability of this crystal has stimulated
new activities exploiting its interesting properties. Potential
applications include wavelength selectable medical procedures
and a wide variety of spectroscopic applications. It is useful
for high performance IR waveplates. It has also been shown as
an excellent crystal for non-linear three-wave interactions.
APPLICATIONS:
• Generation second harmonics on CO and CO2
- lasers
• Optical parametric oscilator
• Different frequency generator to middle
infrared regions up to 12 mkm.
• Frequency mixing in the middle IR region
from 4.0 to 18.3 µm
• Tuneable solid state lasers (OPO pumped
by Nd:YAG and others lasers operating in 1200 to 10000 nm region
with efficiency 0.1 to 10 %)
• Optical narrow-band filters in the region
near isotropic point (0.4974 m at 300 °K), transmission band
being tuned at temperature variation
• Up-conversion of CO2 laser radiation image
into near-IR or visible region by using/ or use of Nd:YAG, ruby
or dye lasers with efficiency up to 30 %
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